Qi, R. et al. Perfect Coulomb drag and exciton transport in an excitonic insulator. Science 388, 278–283 https://doi.org/10.1126/science.adl1839 (2025).
Nguyen, P. X. et al. Perfect Coulomb drag in a dipolar excitonic insulator. Science 388, 274–278 https://doi.org/10.1126/science.adl1829 (2025).
Zhang, Z. et al. Correlated interlayer exciton insulator in heterostructures of monolayer WSe2 and moiré WS2/WSe2. Nat. Phys. 18, 1214–1220 https://doi.org/10.1038/s41567-022-01702-z (2022).
Chen, D. et al. Excitonic insulator in a heterojunction moiré superlattice. Nat. Phys. 18, 1171–1176 https://doi.org/10.1038/s41567-022-01703-y (2022).
Sun, B. et al. Evidence for equilibrium exciton condensation in monolayer WTe2. Nat. Phys. 18, 94–99 https://doi.org/10.1038/s41567-021-01427-5 (2022).
Jia, Y. et al. Evidence for a monolayer excitonic insulator. Nat. Phys. 18, 87–93 https://doi.org/10.1038/s41567-021-01422-w (2022).
Spielman, I. B., Eisenstein, J. P., Pfeiffer, L. N. & West, K. W. Resonantly enhanced tunneling in a double layer quantum hall ferromagnet. Phys. Rev. Lett. 84, 5808 https://doi.org/10.1103/PhysRevLett.84.5808 (2000).
Kellogg, M., Eisenstein, J. P., Pfeiffer, L. N. & West, K. W. Vanishing Hall resistance at high magnetic field in a double-layer two-dimensional electron system. Phys. Rev. Lett. 93, 036801 https://doi.org/10.1103/PhysRevLett.93.036801 (2004).
Tutuc, E., Shayegan, M. & Huse, D. A. Counterflow measurements in strongly correlated GaAs hole bilayers: evidence for electron-hole pairing. Phys. Rev. Lett. 93, 036802 https://doi.org/10.1103/PhysRevLett.93.036802 (2004).
Kohn, W. & Sherrington, D. Two kinds of bosons and Bose condensates. Rev. Mod. Phys. 42, 1 https://doi.org/10.1103/RevModPhys.42.1 (1970).
Eisenstein, J. P. & MacDonald, A. H. Bose–Einstein condensation of excitons in bilayer electron systems. Nature 432, 691–694 https://doi.org/10.1038/nature03081 (2004).
Hughes, H. P. Structural distortion in TiSe2 and related materials-a possible Jahn-Teller effect? J. Phys. C 10, L319 https://doi.org/10.1088/0022-3719/10/11/009 (1977).
Rossnagel, K., Kipp, L. & Skibowski, M. Charge-density-wave phase transition in 1T-TiSe2: excitonic insulator versus band-type Jahn-Teller mechanism. Phys. Rev. B 65, 235101 https://doi.org/10.1103/PhysRevB.65.235101 (2002).
Cercellier, H. et al. Evidence for an excitonic insulator phase in 1T-TiSe2. Phys. Rev. Lett. 99, 146403 https://doi.org/10.1103/PhysRevLett.99.146403 (2007).
Monney, C. et al. Temperature-dependent photoemission on 1T-TiSe2: interpretation within the exciton condensate phase model. Phys. Rev. B 81, 155104 https://doi.org/10.1103/PhysRevB.81.155104 (2010).
Lian, C., Zhang, S.-J., Hu, S.-Q., Guan, M.-X. & Meng, S. Ultrafast charge ordering by self-amplified exciton-phonon dynamics in TiSe2. Nat. Commun. 11, 43 https://doi.org/10.1038/s41467-019-13672-7 (2020).
Ou, Y. et al. Incoherence-to-coherence crossover observed in charge-density-wave material 1T-TiSe2. Nat. Commun. 15, 9202 https://doi.org/10.1038/s41467-024-53647-x (2024).
Kaneko, T. & Ohta, Y. A new era of excitonic insulators. J. Phys. Soc. Jpn 94, 012001 https://doi.org/10.7566/JPSJ.94.012001 (2025).
Kogar, A. et al. Signatures of exciton condensation in a transition metal dichalcogenide. Science 358, 1314–1317 https://doi.org/10.1126/science.aam6432 (2017).
Rohwer, T. et al. Collapse of long-range charge order tracked by time-resolved photoemission at high momenta. Nature 471, 490–493 https://doi.org/10.1038/nature09829 (2011).
Hellmann, S., Rohwer, T., Kalläne, M., Hanff, K. & Sohrt, C. et al. Time-domain classification of charge-density-wave insulators. Nat. Commun. 3, 1069 https://doi.org/10.1038/ncomms2078 (2012).
Porer, M. et al. Non-thermal separation of electronic and structural orders in a persisting charge density wave. Nat. Mater. 13, 857–861 https://doi.org/10.1038/nmat4042 (2014).
Mathias, S. et al. Self-amplified photo-induced gap quenching in a correlated electron material. Nat. Commun. 7, 12902 https://doi.org/10.1038/ncomms12902 (2016).
Monney, C. et al. Revealing the role of electrons and phonons in the ultrafast recovery of charge density wave correlations in 1T-TiSe2. Phys. Rev. B 94, 165165 https://doi.org/10.1103/PhysRevB.94.165165 (2016).
Chen, P. et al. Hidden order and dimensional crossover of the charge density waves in TiSe2. Sci. Rep. 6, 37910 https://doi.org/10.1038/srep37910 (2016).
Cheng, Y., Zong, A., Li, J., Xia, W. & Duan, S. et al. Light-induced dimension crossover dictated by excitonic correlations. Nat. Commun. 13, 963 https://doi.org/10.1038/s41467-022-28309-5 (2022).
Lian, C., Ali, Z. A. & Wong, B. M. Charge density wave hampers exciton condensation in 1T-TiSe2. Phys. Rev. B 100, 205423 https://doi.org/10.1103/PhysRevB.100.205423 (2019).
Otto, M. R. et al. Mechanisms of electron-phonon coupling unraveled in momentum and time: the case of soft phonons in TiSe2. Sci. Adv. 7, eabf2810 https://doi.org/10.1126/sciadv.abf2810 (2021).
Buchberger, S. et al. Persistence of charge ordering instability to Coulomb engineering in the excitonic insulator candidate TiSe2. Phys. Rev. X 15, 041028 https://doi.org/10.1103/9trc-9865 (2025).
Lin, Z. et al. Dramatic plasmon response to the charge-density-wave gap development in 1T-TiSe2. Phys. Rev. Lett. 129, 187601 https://doi.org/10.1103/PhysRevLett.129.187601 (2022).
Geneaux, R., Marroux, H. J. B., Guggenmos, A., Neumark, D. M. & Leone, S. R. Transient absorption spectroscopy using high harmonic generation: a review of ultrafast X-ray dynamics in molecules and solids. Phil. Trans. R. Soc. A 377, 20170463 https://doi.org/10.1098/rsta.2017.0463 (2019).
Zong, A., Nebgen, B. R., Lin, S.-C., Spies, J. A. & Zuerch, M. Emerging ultrafast techniques for studying quantum materials. Nat. Rev. Mater. 8, 224 https://doi.org/10.1038/s41578-022-00530-0 (2023).
Lin, S.-C. et al. A table-top few-femtosecond broadband extreme-ultraviolet absorption spectrometer with cryogenic cooling. Preprint at https://doi.org/10.48550/arXiv.2608.03955 (2026).
Heinrich, T. et al. Electronic and structural fingerprints of charge-density-wave excitations in extreme ultraviolet transient absorption spectroscopy. Phys. Rev. X 13, 021033 https://doi.org/10.1103/PhysRevX.13.021033 (2023).
Mohr-Vorobeva, E. et al. Nonthermal melting of a charge density wave in tise2. Phys. Rev. Lett. 107, 036403 https://doi.org/10.1103/PhysRevLett.107.036403 (2011).
Holy, J. A., Woo, K. C., Klein, M. V. & Brown, F. C. Raman and infrared studies of superlattice formation in TiSe2. Phys. Rev. B 16, 3628 https://doi.org/10.1103/PhysRevB.16.3628 (1977).
Volkov, M. et al. Attosecond screening dynamics mediated by electron localization in transition metals. Nat. Phys. 15, 1145–1149 https://doi.org/10.1038/s41567-019-0602-9 (2019).
Schumacher, Z. et al. Ultrafast electron localization and screening in a transition metal dichalcogenide. Proc. Natl. Acad. Sci. USA 120, 2017 https://doi.org/10.1073/pnas.2221725120 (2023).
Okazaki, K., Ogawa, Y., Suzuki, T., Yamamoto, T. & Someya, T. et al. Photo-induced semimetallic states realised in electron–hole coupled insulators. Nat. Commun. 9, 4322 https://doi.org/10.1038/s41467-018-06801-1 (2018).
Holt, M., Zschack, P., Hong, H., Chou, M. Y. & Chiang, T.-C. X-ray studies of phonon softening in TiSe2. Phys. Rev. Lett. 86, 3799 https://doi.org/10.1103/PhysRevLett.86.3799 (2001).
van Wezel, J., Nahai-Williamson, P. & Saxena, S. S. Exciton-phonon-driven charge density wave in TiSe2. Phys. Rev. B 81, 165109 https://doi.org/10.1103/PhysRevB.81.165109 (2010).
Hedayat, H., Sayers, C. J., Bugini, D., Dallera, C. & Wolverson, D. et al. Excitonic and lattice contributions to the charge density wave in 1T-TiSe2 revealed by a phonon bottleneck. Phys. Rev. Res. 1, 023029 https://doi.org/10.1103/PhysRevResearch.1.023029 (2019).
Cheng, Y., Zong, A., Wu, L., Meng, Q. & Xia, W. et al. Ultrafast formation of topological defects in a two-dimensional charge density wave. Nat. Phys. 20, 54–60 https://doi.org/10.1038/s41567-023-02279-x (2024).
Fragkos, S. et al. Electron-phonon-dominated charge-density-wave fluctuations in TiSe2 accessed by ultrafast nonequilibrium dynamics. Commun. Phys. 9, 86 https://doi.org/10.1038/s42005-026-02521-x (2026).
Wakisaka, Y. et al. Excitonic insulator state in Ta2NiSe5 probed by photoemission spectroscopy. Phys. Rev. Lett. 103, 026402 https://doi.org/10.1103/PhysRevLett.103.026402 (2009).
Kaneko, T., Toriyama, T., Konishi, T. & Ohta, Y. Orthorhombic-to-monoclinic phase transition of Ta2NiSe5 induced by the Bose-Einstein condensation of excitons. Phys. Rev. B 87, 035121 https://doi.org/10.1103/PhysRevB.87.035121 (2013).
Baldini, E. et al. The spontaneous symmetry breaking in Ta2NiSe5 is structural in nature. Proc. Natl. Acad. Sci. USA 120, e2221688120 https://doi.org/10.1073/pnas.2221688120 (2023).
Chen, Z. et al. Structural contribution to light-induced gap suppression in Ta2NiSe5. Phys. Rev. Lett. 135, 096901 https://doi.org/10.1103/1kzk-sz7g (2025).
Zhang, P. et al. Spontaneous gap opening and potential excitonic states in an ideal Dirac semimetal Ta2Pd3Te5. Phys, Rev. X 14, 011047 https://doi.org/10.1103/PhysRevX.14.011047 (2024).
Huang, J. et al. Evidence for an excitonic insulator state in Ta2Pd3Te5. Phys. Rev. X 14, 011046 https://doi.org/10.1103/PhysRevX.14.011046 (2024).
Shafayat Hossain, M. et al. Topological excitonic insulator with tunable momentum order. Nat. Phys. 21, 1250–1259 https://doi.org/10.1038/s41567-025-02917-6 (2025).
Wang, W. et al. Revisiting the charge-density-wave superlattice of 1T−TiSe2. Phys. Rev. Lett. 136, 256101 https://doi.org/10.1103/btvb-ngy5 (2026).
Zong, A. et al. Data from: core-level signature of long-range density-wave order and short-range excitonic correlations probed by attosecond broadband spectroscopy. Dryad https://doi.org/10.5061/dryad.cc2fqz6n8 (2026).