{"id":248168,"date":"2025-10-29T15:48:17","date_gmt":"2025-10-29T15:48:17","guid":{"rendered":"https:\/\/www.newsbeep.com\/ca\/248168\/"},"modified":"2025-10-29T15:48:17","modified_gmt":"2025-10-29T15:48:17","slug":"giant-shot-noise-in-superconductor-ferromagnet-junctions-with-orbital-symmetry-controlled-spin-orbit-coupling","status":"publish","type":"post","link":"https:\/\/www.newsbeep.com\/ca\/248168\/","title":{"rendered":"Giant shot noise in superconductor\/ferromagnet junctions with orbital-symmetry- controlled spin-orbit coupling"},"content":{"rendered":"<p>Our choice of epitaxial V(100)\/MgO\/Fe(100) junctions appears surprising. The incompatible orbital symmetries in the electronic structure of V(100) and Fe(100), suggest that their junctions are nonconducting in the low-bias regime<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Butler, W. H., Zhang, X.-G., Schulthess, T. C. &amp; MacLaren, J. M. Spin-dependent tunneling conductance of Fe\/MgO\/Fe sandwiches. Phys. Rev. B 63, 054416 (2001).\" href=\"#ref-CR33\" id=\"ref-link-section-d38842562e702\">33<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Parkin, S. S. P. et al. Giant tunneling magnetoresistance at room temperature with MgO (100) tunnel barriers. Nat. Mater. 3, 862&#x2013;867 (2004).\" href=\"#ref-CR34\" id=\"ref-link-section-d38842562e702_1\">34<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 35\" title=\"Yuasa, S., Nagahama, T., Fukushima, A., Suzuki, Y. &amp; Ando, K. Giant room temperature magneto-resistance in single-crystal Fe\/MgO\/Fe magnetic tunnel junctions. Nat. Mater. 3, 868&#x2013;871 (2004).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR35\" id=\"ref-link-section-d38842562e705\" rel=\"nofollow noopener\" target=\"_blank\">35<\/a>. Early experiments on heteroepitaxial superconducting Fe\/V\/Fe junctions reveal the importance of the relevant orbital symmetries and how they can determine desirable spin-dependent transport properties<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 36\" title=\"Miao, G.-X., Ramos, A. V. &amp; Moodera, J. S. Infinite magnetoresistance from the spin dependent proximity effect in symmetry driven bcc&#x2212;Fe\/V\/Fe heteroepitaxial superconducting spin valves. Phys. Rev. Lett. 101, 137001 (2008).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR36\" id=\"ref-link-section-d38842562e709\" rel=\"nofollow noopener\" target=\"_blank\">36<\/a>.<\/p>\n<p>At the Fermi level EF, \u03942 orbital symmetry of V is absent for Fe, which is characterized by \u03941 symmetry, shown in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1a<\/a>. Since MgO is an insulator filtering out \u03942 and producing giant tunneling magnetoresistance (TMR) in Fe\/MgO\/Fe junctions<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Butler, W. H., Zhang, X.-G., Schulthess, T. C. &amp; MacLaren, J. M. Spin-dependent tunneling conductance of Fe\/MgO\/Fe sandwiches. Phys. Rev. B 63, 054416 (2001).\" href=\"#ref-CR33\" id=\"ref-link-section-d38842562e732\">33<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Parkin, S. S. P. et al. Giant tunneling magnetoresistance at room temperature with MgO (100) tunnel barriers. Nat. Mater. 3, 862&#x2013;867 (2004).\" href=\"#ref-CR34\" id=\"ref-link-section-d38842562e732_1\">34<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 35\" title=\"Yuasa, S., Nagahama, T., Fukushima, A., Suzuki, Y. &amp; Ando, K. Giant room temperature magneto-resistance in single-crystal Fe\/MgO\/Fe magnetic tunnel junctions. Nat. Mater. 3, 868&#x2013;871 (2004).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR35\" id=\"ref-link-section-d38842562e735\" rel=\"nofollow noopener\" target=\"_blank\">35<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 37\" title=\"Lu, Y. et al. Spin-orbit coupling effect by minority interface resonance states in single-crystal magnetic tunnel junctions. Phys. Rev. B 86, 184420 (2012).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR37\" id=\"ref-link-section-d38842562e738\" rel=\"nofollow noopener\" target=\"_blank\">37<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 38\" title=\"Guerrero, R., Herranz, D. &amp; Aliev, F. G. High bias voltage effect on spin-dependent conductivity and shot noise in carbon-doped Fe(001)\/MgO(001)\/Fe(001) magnetic tunnel junctions. Appl. Phys. Lett. 91, 132504 (2007).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR38\" id=\"ref-link-section-d38842562e741\" rel=\"nofollow noopener\" target=\"_blank\">38<\/a>, proximity-induced superconductivity from V across MgO into Fe seems even less likely. However, structural inversion asymmetry in our junctions leads to interfacial SOC, which accompanies the effective \u03942 barrier in crystalline MgO due to its filtering effect. The SOC-induced spin-flip scattering mixes \u03942 and \u03941 symmetries and creates a mechanism for electron tunneling above TC across the junction at low bias, shown in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1a<\/a>. Our first-principles calculations (see Supplementary Information, Section I, SI-I) also confirm the presence of Rashba SOC at the V\/MgO interfaces. Another low-bias contribution in these epitaxial junctions with conserved wave vector parallel to the interfaces, k||, comes from \u201chot spots\u201d for normal incidence at k||\u2009=\u20090 (the \u0393 point), which provides high transmission through MgO<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 33\" title=\"Butler, W. H., Zhang, X.-G., Schulthess, T. C. &amp; MacLaren, J. M. Spin-dependent tunneling conductance of Fe\/MgO\/Fe sandwiches. Phys. Rev. B 63, 054416 (2001).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR33\" id=\"ref-link-section-d38842562e769\" rel=\"nofollow noopener\" target=\"_blank\">33<\/a>. A simple picture for the normal-state transport in this junction is described by an equivalent resistance, Req\u2009=\u2009RSOC\u2009+\u2009RMgO, in which the resistance of the symmetry-related SOC barrier, RSOC, is much larger than the resistance from the conventional barrier strength of the MgO region, RMgO.<\/p>\n<p>Fig. 1: Orbital symmetry change and normal-state transport in epitaxial V\/MgO\/Fe-based junctions.<a class=\"c-article-section__figure-link\" data-test=\"img-link\" data-track=\"click\" data-track-label=\"image\" data-track-action=\"view figure\" href=\"https:\/\/www.nature.com\/articles\/s41467-025-64493-w\/figures\/1\" rel=\"nofollow noopener\" target=\"_blank\"><img decoding=\"async\" aria-describedby=\"Fig1\" src=\"https:\/\/www.newsbeep.com\/ca\/wp-content\/uploads\/2025\/10\/41467_2025_64493_Fig1_HTML.png\" alt=\"figure 1\" loading=\"lazy\" width=\"685\" height=\"387\"\/><\/a><\/p>\n<p>a The main conductance bands, labeled with their respective orbital symmetries, are superimposed to each region. Arrows denote electron spin. At the Fermi level, EF, in vanadium, only electrons with \u03942 symmetry are present, while they are absent in iron. Therefore, a symmetry change is necessary for the electron transport across the V\/MgO\/Fe junction. This is enabled by the Rashba spin-orbit coupling (SOC) at the V\/MgO interface. MgO acts both as (i) symmetry filter at EF, relatively transparent for \u03941 electrons in iron at the normal incidence (vanishing wave vector along the interface, k|| = 0), while having a strong barrier for \u03942 electrons and (ii) enabling the symmetry and spin changes allowing electron tunneling into the iron. An equivalent resistor model indicates that the SOC barrier dominates over the usual barrier from the MgO region. b Typical normal-state conductance of different tunnel junctions of a lateral size 20 \u00d7 20 \u03bcm2, as a function of their number of V\/MgO barriers. Each dot: sample-averaged conductance. Each extra V\/MgO barrier diminishes the conductance by an order of magnitude. c In-plane tunnel magnetoresistance (TMR) of a spin-valve junction (inset), showing parallel and antiparallel magnetization configurations, changing with an applied magnetic field, H, and the typical coercive field of the hard Fe\/Co magnetic layer. d Across the less-resistive Fe\/MgO\/Fe junction, the transport is dominated by \u03941 electrons without SOC barrier. e, f The absence (presence) of SOC removes (enables) orbital symmetry mixing, explaining the measured relative magnitudes of conductance in (b).<\/p>\n<p>This picture of the tunneling dominated by symmetry-enforced spin filtering, rather than by the barrier strength, is confirmed by the measured low-bias differential conductance G shown in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1b<\/a>, revealing the key role of SOC at the V\/MgO interface. Compared to junctions without such an interface, G is reduced by two (three) orders of magnitude with one (two) interface(s). For in-plane magnetization in a V\/MgO\/Fe\/MgO\/Fe\/Co junction, shown in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1c<\/a>, the obtained TMR\u2009=\u2009(GP &#8211; GAP)\/GAP~40%, where GP (GAP) corresponds to parallel (antiparallel) magnetization in the two Fe regions, signals highly spin-polarized electrons. By excluding the nonmagnetic V\/MgO region, we have shown an even higher TMR~330% in Fe\/MgO\/Fe\/Co junctions<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 38\" title=\"Guerrero, R., Herranz, D. &amp; Aliev, F. G. High bias voltage effect on spin-dependent conductivity and shot noise in carbon-doped Fe(001)\/MgO(001)\/Fe(001) magnetic tunnel junctions. Appl. Phys. Lett. 91, 132504 (2007).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR38\" id=\"ref-link-section-d38842562e889\" rel=\"nofollow noopener\" target=\"_blank\">38<\/a>. Using shot noise measurements, we can also exclude the role of pinholes in determining G (details of sample fabrication, measurements, and characterization can be found in Methods, SI-II and Ref. <a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 31\" title=\"Mart&#xED;nez, I. et al. Interfacial spin-orbit coupling: A platform for superconducting spintronics. Phys. Rev. Appl. 13, 014030 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR31\" id=\"ref-link-section-d38842562e896\" rel=\"nofollow noopener\" target=\"_blank\">31<\/a>). To further support our conductance measurements across different junctions, it is helpful to consider a schematic illustration of the role of dominant orbital symmetries and their SOC-induced mixing in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1<\/a>d\u2013f. The highest measured conductance in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1b<\/a> is found for the Fe\/MgO\/Fe-based junction in which the dominant \u03941 symmetry is shared by all the regions and the related transport does not experience the symmetry mismatch (no SOC barrier). However, for junctions with regions characterized by other orbital symmetries, the spin-filtering exclusion from the MgO can be overcome by SOC mixing and accompanied by a large RSOC, consistent with the results in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1b<\/a>.<\/p>\n<p>In the superconducting state, as shown in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a>, transport is distinguished by Andreev reflection, providing the microscopic mechanism for proximity-induced superconductivity<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 13\" title=\"&#x17D;uti&#x107;, I., Matos-Abiague, A., Scharf, B., Dery, H. &amp; Belashchenko, K. Proximitized materials. Mater. Today 22, 85&#x2013;107 (2019).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR13\" id=\"ref-link-section-d38842562e920\" rel=\"nofollow noopener\" target=\"_blank\">13<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e923\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>. In conventional Andreev reflection, an electron is reflected backwards and converted into a hole of opposite charge and spin. With no interfacial barrier, this implies the doubling of the normal-state GN: two electrons are transferred across the interface into S, where they form a spin-singlet Cooper pair<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 39\" title=\"Blonder, G. E., Tinkham, M. &amp; Klapwijk, T. M. Transition from metallic to tunneling regimes in superconducting microconstrictions: Excess current, charge imbalance, and supercurrent conversion. Phys. Rev. B 25, 4515&#x2013;4532 (1982).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR39\" id=\"ref-link-section-d38842562e931\" rel=\"nofollow noopener\" target=\"_blank\">39<\/a>. Because of spin polarization P in F, not all electrons can find a partner of opposite spin to undergo Andreev reflection<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e939\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 40\" title=\"&#x17D;uti&#x107;, I. &amp; Das Sarma, S. Spin-polarized transport and Andreev reflection in semi-conductor\/ superconductor hybrid structures. Phys. Rev. B 60, R16322&#x2013;R16325 (1999).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR40\" id=\"ref-link-section-d38842562e942\" rel=\"nofollow noopener\" target=\"_blank\">40<\/a>. Together with the normal (ordinary) reflection at the interfacial barrier, such a finite P suppresses the Andreev reflection and reduces G<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 40\" title=\"&#x17D;uti&#x107;, I. &amp; Das Sarma, S. Spin-polarized transport and Andreev reflection in semi-conductor\/ superconductor hybrid structures. Phys. Rev. B 60, R16322&#x2013;R16325 (1999).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR40\" id=\"ref-link-section-d38842562e951\" rel=\"nofollow noopener\" target=\"_blank\">40<\/a> at applied bias V&lt;\u0394\/e below the effective superconducting gap \u0394 ~1.05\u2009meV, where -e is the electron charge. A small peak in G(V\\( \\sim \\)\u0394\/e) and a substantial value of G(V\u2009=\u20090) (Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a>) suggest that S\/F is not a typical tunnel junction and has only a moderate interfacial barrier strength. The inset in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a> indicates TC\u2009~\u20094\u2009K, as identified by the measured temperature-dependent conductance.<\/p>\n<p>Fig. 2: Bias dependence of the conductance and giant shot noise in a V\/MgO\/Fe junction.<a class=\"c-article-section__figure-link\" data-test=\"img-link\" data-track=\"click\" data-track-label=\"image\" data-track-action=\"view figure\" href=\"https:\/\/www.nature.com\/articles\/s41467-025-64493-w\/figures\/2\" rel=\"nofollow noopener\" target=\"_blank\"><img decoding=\"async\" aria-describedby=\"Fig2\" src=\"https:\/\/www.newsbeep.com\/ca\/wp-content\/uploads\/2025\/10\/41467_2025_64493_Fig2_HTML.png\" alt=\"figure 2\" loading=\"lazy\" width=\"685\" height=\"379\"\/><\/a><\/p>\n<p>a Conductance for a superconductor\/ferromagnet (S\/F) sample (sketched in the left), above (red) and below (blue) the critical temperature of vanadium, TC, normalized by the conductance at bias V\u2009=\u2009\u22125 mV, above the effective superconducting gap, \u0394, -e is the electron charge. Inset: TC identified by the measured temperature-dependent subgap conductance. b For the same sample, there is giant shot noise below TC (blue) at low bias, eV &lt; \u0394, compared to its value above TC (red), and its corresponding theoretical maximum value given by the Fano factor, F\u2009=\u20091 (green), for the normal state. c The evolution of the shot noise power with frequency, f, and V, shown in the logarithmic scale. The noise spectrum is largely f independent, except near the lowest f. d, e Comparison of the bias-dependent conductance and shot noise with the control V\/MgO\/Au junction, with the same normalization as in (a). f Schematic role of the MgO\/Au nonepitaxial growth leading to the highly textured interface and suppressed filtering due to different orbital symmetries.<\/p>\n<p>A high-quality MgO barrier defines the location of the voltage drop and thus enables accurate shot noise measurements, previously absent in S\/F junctions. Unlike the measured G(V), similar to what was observed in various superconducting structures, the shot noise in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2b<\/a> for the same S\/F junction shows an unprecedented giant low-bias increase at T\u2009=\u20090.3\u2009K\u2009&lt;\u2009TC, orders of magnitude larger than theoretically expected. With fluctuations due to the discreteness of the electrical charge, it is common to introduce the current shot noise power SI,max\u2009=\u20092q\u2009&lt;\u2009I&gt; transferred in discrete units of charge q, where &lt;I&gt; is the average current<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Blanter, Y.aM. &amp; Buttiker, M. Shot noise in mesoscopic conductors. Phys. Rep. 336, 1&#x2013;166 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR10\" id=\"ref-link-section-d38842562e1127\" rel=\"nofollow noopener\" target=\"_blank\">10<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 11\" title=\"Beenakker, C. &amp; Schonenberger, C. Quantum shot noise. Phys. Today 56, 37&#x2013;42 (2003).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR11\" id=\"ref-link-section-d38842562e1130\" rel=\"nofollow noopener\" target=\"_blank\">11<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 41\" title=\"Niu, J. et al. Why shot noise does not generally detect pairing in mesoscopic superconducting tunnel junctions. Phys. Rev. Lett. 132, 076001 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR41\" id=\"ref-link-section-d38842562e1133\" rel=\"nofollow noopener\" target=\"_blank\">41<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 42\" title=\"Aliev F. G. &amp; Cascales, J. P. Noise in Spintronics: From Understanding to Manipulation (Stanford Publishing, 2018).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR42\" id=\"ref-link-section-d38842562e1136\" rel=\"nofollow noopener\" target=\"_blank\">42<\/a>. To describe the ratio between the shot noise and the conductance, it is useful to introduce the Fano factor<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Blanter, Y.aM. &amp; Buttiker, M. Shot noise in mesoscopic conductors. Phys. Rep. 336, 1&#x2013;166 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR10\" id=\"ref-link-section-d38842562e1141\" rel=\"nofollow noopener\" target=\"_blank\">10<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 11\" title=\"Beenakker, C. &amp; Schonenberger, C. Quantum shot noise. Phys. Today 56, 37&#x2013;42 (2003).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR11\" id=\"ref-link-section-d38842562e1144\" rel=\"nofollow noopener\" target=\"_blank\">11<\/a> F\u2009=\u2009SI\/(2eG\u2009|\u2009V\u2009|\u2009). This Fano factor also gives the effective charge responsible for the shot noise<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Blanter, Y.aM. &amp; Buttiker, M. Shot noise in mesoscopic conductors. Phys. Rep. 336, 1&#x2013;166 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR10\" id=\"ref-link-section-d38842562e1164\" rel=\"nofollow noopener\" target=\"_blank\">10<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 11\" title=\"Beenakker, C. &amp; Schonenberger, C. Quantum shot noise. Phys. Today 56, 37&#x2013;42 (2003).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR11\" id=\"ref-link-section-d38842562e1167\" rel=\"nofollow noopener\" target=\"_blank\">11<\/a>. For a fully random (Poisson) process of uncorrelated electrons, SPoisson\u2009=\u20092e&lt;I\u2009&gt;\u2009, F in the normal state attains at maximum F\u2009=\u20091, while F\u2009=\u20092 for superconducting tunnel junctions<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 11\" title=\"Beenakker, C. &amp; Schonenberger, C. Quantum shot noise. Phys. Today 56, 37&#x2013;42 (2003).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR11\" id=\"ref-link-section-d38842562e1188\" rel=\"nofollow noopener\" target=\"_blank\">11<\/a> signals that |q\u2009|\u2009= 2e since the shot noise originates from the transfer of Cooper pairs. With a finite circuit resistance, our measurements also include voltage fluctuations with the resulting voltage shot noise power<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Blanter, Y.aM. &amp; Buttiker, M. Shot noise in mesoscopic conductors. Phys. Rep. 336, 1&#x2013;166 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR10\" id=\"ref-link-section-d38842562e1195\" rel=\"nofollow noopener\" target=\"_blank\">10<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 42\" title=\"Aliev F. G. &amp; Cascales, J. P. Noise in Spintronics: From Understanding to Manipulation (Stanford Publishing, 2018).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR42\" id=\"ref-link-section-d38842562e1198\" rel=\"nofollow noopener\" target=\"_blank\">42<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 43\" title=\"Anton, S. M. et al. Magnetic flux noise in dc SQUIDs: Temperature and geometry dependence. Phys. Rev. Lett. 110, 147002 (2013).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR43\" id=\"ref-link-section-d38842562e1201\" rel=\"nofollow noopener\" target=\"_blank\">43<\/a> SV\u2009=\u2009F2e\u2009&lt;\u2009I\u2009&gt;\u2009\/G2 (SI-II provides the expression for T\u2009&gt;\u20090), shown together with the expected maximum normal-state value for F\u2009=\u20091. Remarkably, at T\u2009=\u20090.3\u2009K and eV\u2009&lt;\u2009\u0394, we can infer F\u2009&gt;\u2009100, as if a giant effective charge |q\u2009|\u2009&gt; 100 e is responsible for the observed shot noise! This striking behavior is the hallmark of the superconducting state, while at eV\u2009&gt;\u2009\u0394 or T\u2009&gt;\u2009TC, SV approaches the Poisson value for F\u2009=\u20091 (green line). Another distinguishing feature of the giant SV in the superconducting state is its independence of frequency f, shown in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2c<\/a> over two orders of magnitude in the frequency range. In contrast, the contribution of vortices<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 43\" title=\"Anton, S. M. et al. Magnetic flux noise in dc SQUIDs: Temperature and geometry dependence. Phys. Rev. Lett. 110, 147002 (2013).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR43\" id=\"ref-link-section-d38842562e1273\" rel=\"nofollow noopener\" target=\"_blank\">43<\/a> is reflected in the 1\/f-dependent part of the noise, decreasing with f and increasing with T, when T approaches TC (SI-III).<\/p>\n<p>It is helpful to compare our prior conductance and shot noise results for S\/I\/F (V\/MgO\/Fe) junction with the measurements on a control S\/I\/N junction (V\/MgO\/Au). As expected, in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2d<\/a> we find that the low-bias conductance is suppressed less in V\/MgO\/Au than that in V\/MgO\/Fe junction, consistent with the nonmagnetic Au and P\u2009=\u20090, as the Andreev reflection does not experience a large suppression from P\u2009=\u20090.7 at the Fe\/MgO interface. Both junctions are not in a typical tunneling regime and they share only a small peak in G, known to appear at V\\( \\sim \\)\u0394\/e. However, the separation of the two peaks is larger in V\/MgO\/Fe where, considering the commonly expected competition between ferromagnetism and superconductivity<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e1332\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 21\" title=\"Buzdin, A. I. Proximity effects in superconductor-ferromagnet heterostructures. Rev. Mod. Phys. 77, 935&#x2013;976 (2005).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR21\" id=\"ref-link-section-d38842562e1335\" rel=\"nofollow noopener\" target=\"_blank\">21<\/a>, such a separation and the related superconducting gap should be reduced compared to the one in nonmagnetic V\/MgO\/Au. Since in both junctions we see that the superconducting gap exceeds the values expected for V itself, a larger peak separation in V\/MgO\/Fe would be consistent with a slightly larger proximity-induced gap than in V\/MgO\/Au (see discussion below). While the changes in the two corresponding gaps are moderate, turning to the comparison of the shot noise in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2e<\/a>, we see a drastic increase in the measured low-bias shot noise of the V\/MgO\/Fe junction. These trends in the conductance and shot noise by replacing F by N region can be partially understood by recognizing the importance of the epitaxial growth and high-quality interfaces in V\/MgO\/Fe, while V\/MgO\/Au is an example of non-epitaxial growth leading to a highly textured interface and suppressed filtering due to different orbital symmetries, as depicted in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2f<\/a> and SI-II. That the apparent superconducting gap is not more suppressed in V\/MgO\/Fe could signal the presence of spin-triplet superconductivity coexisting with ferromagnetism<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e1345\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 31\" title=\"Mart&#xED;nez, I. et al. Interfacial spin-orbit coupling: A platform for superconducting spintronics. Phys. Rev. Appl. 13, 014030 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR31\" id=\"ref-link-section-d38842562e1348\" rel=\"nofollow noopener\" target=\"_blank\">31<\/a>.<\/p>\n<p>The correlations among electrons, due to Coulomb repulsion and the Pauli exclusion principle, reduce the shot noise below its Poisson limit F\u2009=\u20091 (F\u2009=\u20092) in the normal (superconducting) state<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Blanter, Y.aM. &amp; Buttiker, M. Shot noise in mesoscopic conductors. Phys. Rep. 336, 1&#x2013;166 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR10\" id=\"ref-link-section-d38842562e1361\" rel=\"nofollow noopener\" target=\"_blank\">10<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 11\" title=\"Beenakker, C. &amp; Schonenberger, C. Quantum shot noise. Phys. Today 56, 37&#x2013;42 (2003).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR11\" id=\"ref-link-section-d38842562e1364\" rel=\"nofollow noopener\" target=\"_blank\">11<\/a>. For example, in the fractional quantum Hall effect, the measured F\u2009=\u20091\/3 signals the characteristic fractional charge<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 4\" title=\"Saminadayar, L., Glattli, D. C., Jin, Y. &amp; Etienne, B. Observation of the e\/3 fractionally charged Laughlin quasiparticle. Phys. Rev. Lett. 79, 2526&#x2013;2529 (1997).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR4\" id=\"ref-link-section-d38842562e1371\" rel=\"nofollow noopener\" target=\"_blank\">4<\/a>. Rare exceptions where the shot noise is enhanced compared to the Poisson value<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Ronen, Y. et al. Charge of a quasiparticle in a superconductor. Proc. Natl. Acad. Sci. USA 113, 1743&#x2013;1748 (2016).\" href=\"#ref-CR14\" id=\"ref-link-section-d38842562e1376\">14<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Dieleman, P., Bukkems, H. G., Klapwijk, T. M., Schicke, M. &amp; Gundlach, K. H. Observation of Andreev reflection enhanced shot noise. Phys. Rev. Lett. 79, 3486&#x2013;3489 (1997).\" href=\"#ref-CR15\" id=\"ref-link-section-d38842562e1376_1\">15<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 16\" title=\"Hoss, T. et al. Multiple Andreev reflection and giant excess noise in diffusive superconductor\/normal-metal\/superconductor junctions. Phys. Rev. B 62, 4079&#x2013;4085 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR16\" id=\"ref-link-section-d38842562e1379\" rel=\"nofollow noopener\" target=\"_blank\">16<\/a> are typically observed in junctions with multiple superconducting regions without ferromagnets. To examine such excess shot noise, we consider a V\/MgO\/Fe\/MgO\/Fe\/Co junction, used also to measure TMR in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1c<\/a>. With the two different F regions, we can control the orientation of the Fe magnetization while the higher-coercivity Fe\/Co magnetization remains fixed and serves as a sensor of the Fe magnetization through the measured TMR signal.<\/p>\n<p>For the V\/MgO\/Fe\/MgO\/Fe\/Co junction in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig3\" rel=\"nofollow noopener\" target=\"_blank\">3a<\/a> we see another example of a giant increase in the subgap shot noise, strongly suppressed by the out-of-plane (OOP) applied magnetic field, HOOP. This is further examined in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig3\" rel=\"nofollow noopener\" target=\"_blank\">3b<\/a>, which shows the suppression of the maximum value of the subgap shot noise with both HOOP and in-plane (IP) HIP. A stronger SV suppression with HOOP than with HIP is expected, just as for the OOP H-suppression of \u0394 (in the inset). However, the in-plane anisotropy (between [100] and [110] orientations for both SV and \u0394) is surprising for conventional spin-singlet superconductivity and could instead signal an induced spin-triplet superconductivity. We also observe a slight increase in the noise with HIP, which can be attributed to the field-suppression of inherent magnetic textures. Similar trends in the suppression with V and H are also reproduced in the measured Fano factor in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig3\" rel=\"nofollow noopener\" target=\"_blank\">3c<\/a>, which reaches nearly F\u2009=\u2009200.<\/p>\n<p>Fig. 3: Anisotropic suppression of the giant shot noise by an applied magnetic field and bias.<a class=\"c-article-section__figure-link\" data-test=\"img-link\" data-track=\"click\" data-track-label=\"image\" data-track-action=\"view figure\" href=\"https:\/\/www.nature.com\/articles\/s41467-025-64493-w\/figures\/3\" rel=\"nofollow noopener\" target=\"_blank\"><img decoding=\"async\" aria-describedby=\"Fig3\" src=\"https:\/\/www.newsbeep.com\/ca\/wp-content\/uploads\/2025\/10\/41467_2025_64493_Fig3_HTML.png\" alt=\"figure 3\" loading=\"lazy\" width=\"685\" height=\"198\"\/><\/a><\/p>\n<p>The measured spin-valve junction V\/MgO\/Fe\/MgO\/Fe\/Co is the same as in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1c<\/a>. a Out-of-plane (OOP) magnetic field effectively suppress the superconductivity and the observed low-bias shot noise. b Magnetic-field dependence of the maximum noise shot shows anisotropy, not only between in-plane (IP) and OOP (black), but also for IP easy (red) and hard (green) axis, which is unexpected for a spin-singlet superconductivity. Inset: anisotropic suppression of \u0394 for the same directions of applied magnetic field, H (same legend). c Evolution of the Fano factor, F, with applied bias and magnetic fields. The inset: the maximum Fano factor, FMAX, shown for a wide range of IP (red) and OOP (black) applied fields.<\/p>\n<p>To seek a possible explanation of this peculiar behavior, we recall that normal-state transport in V\/MgO\/Fe-based junctions and our first-principles calculations confirm the presence of the interfacial SOC. Given the measured HIP noise anisotropy, such SOC influences the superconducting state and leads to spin-flip Andreev reflection with equal spin for electrons and holes, which is responsible for spin-triplet Cooper pairs<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e1502\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 44\" title=\"H&#xF6;gl, P., Matos-Abiague, A., &#x17D;uti&#x107;, I. &amp; Fabian, J. Magnetoanisotropic Andreev reflection in ferromagnet\/superconductor junctions. Phys. Rev. Lett. 115, 116601 (2015).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR44\" id=\"ref-link-section-d38842562e1505\" rel=\"nofollow noopener\" target=\"_blank\">44<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 45\" title=\"Vezin, T., Shen, C., Han, J. E. &amp; &#x17D;uti&#x107;, I. Enhanced spin-triplet pairing in magnetic junctions with s-wave superconductors. Phys. Rev. B 101, 014515 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR45\" id=\"ref-link-section-d38842562e1508\" rel=\"nofollow noopener\" target=\"_blank\">45<\/a>. As a result, SOC can partially counteract the suppression of Andreev reflection due to the high spin polarization, P \\( \\sim \\) 0.7\u20130.8, of the Fe\/MgO contact<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 31\" title=\"Mart&#xED;nez, I. et al. Interfacial spin-orbit coupling: A platform for superconducting spintronics. Phys. Rev. Appl. 13, 014030 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR31\" id=\"ref-link-section-d38842562e1533\" rel=\"nofollow noopener\" target=\"_blank\">31<\/a>, and the normalized interfacial barrier strength Z, such that the resulting low-bias G is higher than without SOC<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 45\" title=\"Vezin, T., Shen, C., Han, J. E. &amp; &#x17D;uti&#x107;, I. Enhanced spin-triplet pairing in magnetic junctions with s-wave superconductors. Phys. Rev. B 101, 014515 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR45\" id=\"ref-link-section-d38842562e1544\" rel=\"nofollow noopener\" target=\"_blank\">45<\/a>. This is consistent with the data from Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a>, which indicate only a moderate Z \\( \\sim \\,\\)1 (Z\u2009=\u20090 for perfect transparency and Z \u226b 1 for a tunnel junction). However, when we theoretically explore the shot noise in S\/F junctions over a large parameter space for normalized barrier and Rashba SOC strength Z and \u03bb (see Methods and SI-IVA, B), respectively, the maximum value is F\u2009=\u20092 (SI-IVC), orders of magnitude smaller than in Figs.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2<\/a>b or <a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig3\" rel=\"nofollow noopener\" target=\"_blank\">3c<\/a>. With our analysis of the calculated shot noise in an effective 1D system, in the absence of spin polarization, it is possible to analytically express different scattering coefficients for the S\/N junction and use them to evaluate the enhanced Fano factor for S\/N\/S Josephson junctions (SI-IVD).<\/p>\n<p>The interplay of ferromagnetism and SOC is expected to generate proximity-induced spin-triplet superconductivity, but that alone cannot explain a huge excess of shot noise. Instead, prior examples of large shot noise<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Ronen, Y. et al. Charge of a quasiparticle in a superconductor. Proc. Natl. Acad. Sci. USA 113, 1743&#x2013;1748 (2016).\" href=\"#ref-CR14\" id=\"ref-link-section-d38842562e1598\">14<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Dieleman, P., Bukkems, H. G., Klapwijk, T. M., Schicke, M. &amp; Gundlach, K. H. Observation of Andreev reflection enhanced shot noise. Phys. Rev. Lett. 79, 3486&#x2013;3489 (1997).\" href=\"#ref-CR15\" id=\"ref-link-section-d38842562e1598_1\">15<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 16\" title=\"Hoss, T. et al. Multiple Andreev reflection and giant excess noise in diffusive superconductor\/normal-metal\/superconductor junctions. Phys. Rev. B 62, 4079&#x2013;4085 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR16\" id=\"ref-link-section-d38842562e1601\" rel=\"nofollow noopener\" target=\"_blank\">16<\/a> suggest a resonant behavior which could naturally occur in Josephson junctions, with two superconducting regions and the formation of Andreev bound states, defined by multiple Andreev reflections (MAR)<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 20\" title=\"Tafuri, F. ed. Fundamentals and Frontiers of the Josephson Effect (Springer Nature, Cham, 2019).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR20\" id=\"ref-link-section-d38842562e1605\" rel=\"nofollow noopener\" target=\"_blank\">20<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 46\" title=\"Octavio, M., Tinkham, M., Blonder, G. E. &amp; Klapwijk, T. M. Subharmonic energy-gap structure in superconducting constrictions. Phys. Rev. B 27, 6739&#x2013;6746 (1983).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR46\" id=\"ref-link-section-d38842562e1608\" rel=\"nofollow noopener\" target=\"_blank\">46<\/a>. In the simple case of two identical superconducting gaps and Z\u2009=\u20090, one expects n = \u0394\/eV Andreev reflections, as if the charge transfer and the underlying shot noise could be described by a composite object with effective charge |q\u2009|\u2009= ne<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 47\" title=\"Han, S., Cohen, F. &amp; Wolf, E. L. Apparent critical currents and rf steps in a second-order proximity-induced Josephson effect. Phys. Rev. B 42, 8682&#x2013;8685 (1990).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR47\" id=\"ref-link-section-d38842562e1622\" rel=\"nofollow noopener\" target=\"_blank\">47<\/a>. Support that only a single S region in nonmagnetic junctions could display properties of proximity-induced Josephson effect<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 32\" title=\"Ferrell, R. A. Fluctuations and the superconducting phase transition: II. Onset of Josephson tunneling and paraconductivity of a junction. J. Low. Temp. Phys. 1, 423&#x2013;442 (1969).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR32\" id=\"ref-link-section-d38842562e1626\" rel=\"nofollow noopener\" target=\"_blank\">32<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 47\" title=\"Han, S., Cohen, F. &amp; Wolf, E. L. Apparent critical currents and rf steps in a second-order proximity-induced Josephson effect. Phys. Rev. B 42, 8682&#x2013;8685 (1990).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR47\" id=\"ref-link-section-d38842562e1629\" rel=\"nofollow noopener\" target=\"_blank\">47<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 48\" title=\"Agra&#xEF;t, N., Rodrigo, J. G. &amp; Vieira, S. Transition from the tunneling regime to point contact and proximity-induced Josephson effect in lead-normal-metal nanojunctions. Phys. Rev. B 46, 5814(R)&#x2212;5817(R) (1992).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR48\" id=\"ref-link-section-d38842562e1632\" rel=\"nofollow noopener\" target=\"_blank\">48<\/a> motivates us to revisit the understanding of S\/F junctions. Proximity-induced spin-singlet superconductivity is strongly suppressed in F, such as Fe. However, its SOC-induced spin-triplet counterpart could coexist with ferromagnets, and we also consider that it is accompanied by an effective superconducting gap \u0394F, and therefore supports MAR and enhances F beyond 2. The equal-spin superconducting correlations derived from the superconducting condensate inside V evolve dynamically through the interplay between SOC, symmetry-dependent tunneling, and the exchange interaction. The resulting phase evolution effectively decouples the proximity-induced superconducting correlations from the parent superconductor and supports MAR, which is also observed from preformed pairs<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 6\" title=\"Bastiaans, K. M. et al. Direct evidence for Cooper pairing without a spectral gap in a disordered superconductor above Tc. Science 374, 608&#x2013;611 (2021).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR6\" id=\"ref-link-section-d38842562e1641\" rel=\"nofollow noopener\" target=\"_blank\">6<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 7\" title=\"Zhou, P. et al. Electron pairing in the pseudogap state revealed by shot noise in copper oxide junctions. Nature 572, 493&#x2013;496 (2019).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR7\" id=\"ref-link-section-d38842562e1644\" rel=\"nofollow noopener\" target=\"_blank\">7<\/a>. This is unlike the usual proximity effects in S\/F (S\/N) junctions, where the proximitized order parameter is directly phase locked to that of S<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 21\" title=\"Buzdin, A. I. Proximity effects in superconductor-ferromagnet heterostructures. Rev. Mod. Phys. 77, 935&#x2013;976 (2005).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR21\" id=\"ref-link-section-d38842562e1648\" rel=\"nofollow noopener\" target=\"_blank\">21<\/a>.<\/p>\n<p>A sketch of the physical mechanism for the giant shot noise and induced \u0394F is depicted in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig4\" rel=\"nofollow noopener\" target=\"_blank\">4a<\/a>. The considered multiple electron-hole reflections are consistent with the abundance of these quasiparticles with \u03941 symmetry at the Fermi level of Fe(001), which easily tunnel through the MgO due to hot spots in momentum space. Multiple states with complex wave vectors in the MgO lead to interference effects in G<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 31\" title=\"Mart&#xED;nez, I. et al. Interfacial spin-orbit coupling: A platform for superconducting spintronics. Phys. Rev. Appl. 13, 014030 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR31\" id=\"ref-link-section-d38842562e1665\" rel=\"nofollow noopener\" target=\"_blank\">31<\/a>. The Fano factor gives the effective charge transfer through MAR across the apparent proximity-induced Josephson junction, formed by the vanadium s-wave superconductor and the resulting spin-triplet correlations in Fe. With this picture, we generalize the MAR<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 15\" title=\"Dieleman, P., Bukkems, H. G., Klapwijk, T. M., Schicke, M. &amp; Gundlach, K. H. Observation of Andreev reflection enhanced shot noise. Phys. Rev. Lett. 79, 3486&#x2013;3489 (1997).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR15\" id=\"ref-link-section-d38842562e1673\" rel=\"nofollow noopener\" target=\"_blank\">15<\/a> calculation for G and the Fano factor to include the influence of SOC and normal reflections.<\/p>\n<p>Fig. 4: Physical mechanism with calculated conductance and shot noise.<a class=\"c-article-section__figure-link\" data-test=\"img-link\" data-track=\"click\" data-track-label=\"image\" data-track-action=\"view figure\" href=\"https:\/\/www.nature.com\/articles\/s41467-025-64493-w\/figures\/4\" rel=\"nofollow noopener\" target=\"_blank\"><img decoding=\"async\" aria-describedby=\"Fig4\" src=\"https:\/\/www.newsbeep.com\/ca\/wp-content\/uploads\/2025\/10\/41467_2025_64493_Fig4_HTML.png\" alt=\"figure 4\" loading=\"lazy\" width=\"685\" height=\"184\"\/><\/a><\/p>\n<p>a Proximity-induced superconducting spin-triplet gap in Fe layer (blue), \u0394F, and the interfacial spin-orbit coupling (SOC) support multiple spin-flip Andreev reflections in the V\/MgO\/Fe junction, which give rise to the excess charge transport (5e in the sketch) and the resulting low-bias excess Fano factor, h denotes holes. b Bias-dependent conductance without (black) and with SOC (colored lines) for different relative magnitudes of the induced spin-triplet gap, \u0394F, and the spin-singlet gap, \u0394S, in vanadium. Without SOC, there is a reduced junction transparency and conductance for all V. For comparison with experimental measurements, each curve with SOC is normalized by its conductance value well above the superconducting gap. The barrier and SOC strengths are parameterized by Z\u2009=\u20091 and \u03bb= 1.2 (see Methods). c Calculated Fano factor or, equivalently, the effective charge ratio |q\u2009|\u2009\/e, as a function of applied bias for the same parameters and a color code as given in (b). Inset: The corresponding evolution of the effective charge ratio (at eV\/\u0394s\u2009=\u20090.1) and the conductance peak position with relative increase in \u0394F. The gray area denotes the commonly expected Fano factor limited by 2.<\/p>\n<p>This simple phenomenological model, nevertheless, captures several important experimental observations. With the calculated G in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig4\" rel=\"nofollow noopener\" target=\"_blank\">4b<\/a> we see that SOC enhances the interfacial transparency, consistent with the measurements from Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a> which indicate only a moderate Z \\( \\sim \\) 1, rather than the conventional tunnel junction with Z \u226b 1. By explicitly including \u0394F\u2009&gt;\u20090, we find that MAR-modified G no longer has the usual peak at the pure superconducting gap for vanadium, \u0394S, but is shifted to higher values, eVpeak\u2009=\u2009\u0394S\u2009+\u2009\u0394F. Considering the broadening effect on the G\u2013V curve due to thermal smearing and inelastic scattering in experiments, this peak position could be further shifted to higher energies<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Nadgorny, B. E. Point Contact Andreev Reflection Spectroscopy, in Spintronics Handbook: Spin Transport and Magnetism, 2nd Ed., edited by Tsymbal, E. Y. &amp; &#x17D;uti&#x107;, I. (CRC Press, Boca Raton, FL, 2019), Vol. 3, pp. 35-97.\" href=\"#ref-CR49\" id=\"ref-link-section-d38842562e1788\">49<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Sheet, G., Mukhopadhyay, S. &amp; Raychaudhuri, P. Role of critical current on the point-contact Andreev reflection spectra between a normal metal and a superconductor. Phys. Rev. B 69, 134507 (2004).\" href=\"#ref-CR50\" id=\"ref-link-section-d38842562e1788_1\">50<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 51\" title=\"Shigeta, I. et al. Epitaxial contact Andreev reflection spectroscopy of NbN\/Co2FeSi layered devices. Appl. Phys. Lett. 112, 072402 (2018).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR51\" id=\"ref-link-section-d38842562e1791\" rel=\"nofollow noopener\" target=\"_blank\">51<\/a>, leading to superconducting gaps (\u0394Fe, \u0394Au) in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2d<\/a> that exceed the expected BCS value of \u0394S\u2009=\u20090.7\u2009meV for vanadium with a measured critical temperature of TC ~ 4\u2009K. Assuming that the spin-triplet gap is negligible in the S\/I\/N (V\/MgO\/Au) control junction and, based on the measured gaps (\u0394Fe, \u0394Au) in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2d<\/a>, we find \u0394Fe \/ \u0394Au\u2009=\u2009(\u0394F\u2009+\u2009\u0394S) \/ \u0394S\u2009\u2248\u20091.2, from which we estimate the induced gap \u0394F\u2009\u2248\u200920% \u0394S. With these parameters, we achieve an excellent fit to the experimental conductance (Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a>, SI-IVF). This peak shift effect provides additional evidence for the proximity-induced triplet gap and the Josephson junction-like behavior in the S\/I\/F (V\/MgO\/Fe) junction.<\/p>\n<p>Considering next the Fano factor, which in Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig4\" rel=\"nofollow noopener\" target=\"_blank\">4c<\/a> is represented by |q\u2009|, the calculated effective charge transfer (SI-IVE), we confirm the essential role of proximity-induced \u0394F, while a two-fold change of Z has only a very small influence. A finite \u0394F, through MAR, allows for a large number of electron pairs to be transferred into the superconducting lead, resulting in a giant F near vanishing V. In the opposite large-bias limit, eV\u2009&gt;\u2009\u2206, |q| approaches the uncorrelated limit e, as the current is carried by independent quasiparticles. However, with \u0394F\u2009=\u20090, the higher-order Andreev reflections alternate between the electron and hole pairs transferred into the superconducting lead, without any giant Fano factor. Even at vanishing V, the calculated |q| retains its conventional value of 2, known for S\/N junctions<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Blanter, Y.aM. &amp; Buttiker, M. Shot noise in mesoscopic conductors. Phys. Rep. 336, 1&#x2013;166 (2000).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR10\" id=\"ref-link-section-d38842562e1860\" rel=\"nofollow noopener\" target=\"_blank\">10<\/a>. The inset of Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig4\" rel=\"nofollow noopener\" target=\"_blank\">4c<\/a> shows that the magnitude of the low-bias Fano factor grows with the increasing proximity-induced \u0394F, together with an increased bias value for the peak position in G. Even in the extreme limit of \u0394F\u2009=\u2009\u0394S, our calculated results underestimate the measured Fano factor. We attribute this limitation to our simple and transparent description, which neglects the random scattering from the SOC barrier and the destructive interference<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 52\" title=\"Lee, P. A. &amp; Ramakrishnan, T. V. Disordered electronic systems. Rev. Mod. Phys. 57, 287&#x2013;337 (1985).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR52\" id=\"ref-link-section-d38842562e1877\" rel=\"nofollow noopener\" target=\"_blank\">52<\/a> suppressing the current (and therefore increasing F). Including these omitted effects could provide closer agreement with the measured Fano factor. Nevertheless, our theoretical framework already addresses the observed major puzzle. We provide a mechanism to exceed the expected theoretical limit F\u2009=\u20092 (shown in gray) with a single S region, while using the same parameters that describe the measured G(V) from Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig2\" rel=\"nofollow noopener\" target=\"_blank\">2a<\/a>.<\/p>\n<p>The significance of SOC and orbital symmetry selection in high-quality epitaxial junctions is further verified from our control V\/MgO\/V measurements (SI-II). One may expect that this conventional S\/I\/S Josephson junction would support an even larger Fano factor than in S\/I\/F junctions that we have studied. Indeed, experiments in NbN\/MgO\/NbN junctions confirm MAR and an enhanced shot noise<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 15\" title=\"Dieleman, P., Bukkems, H. G., Klapwijk, T. M., Schicke, M. &amp; Gundlach, K. H. Observation of Andreev reflection enhanced shot noise. Phys. Rev. Lett. 79, 3486&#x2013;3489 (1997).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR15\" id=\"ref-link-section-d38842562e1897\" rel=\"nofollow noopener\" target=\"_blank\">15<\/a>. Instead, with different orbital symmetries in V\/MgO\/V junctions, \u03942 in vanadium and \u03941 in MgO, both the conductance and subgap shot noise are suppressed several orders of magnitude as compared to V\/MgO\/Fe junctions.<\/p>\n<p>These results suggest several important future opportunities. The proximity-induced Josephson effect in N\/I\/S junctions<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 47\" title=\"Han, S., Cohen, F. &amp; Wolf, E. L. Apparent critical currents and rf steps in a second-order proximity-induced Josephson effect. Phys. Rev. B 42, 8682&#x2013;8685 (1990).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR47\" id=\"ref-link-section-d38842562e1908\" rel=\"nofollow noopener\" target=\"_blank\">47<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 48\" title=\"Agra&#xEF;t, N., Rodrigo, J. G. &amp; Vieira, S. Transition from the tunneling regime to point contact and proximity-induced Josephson effect in lead-normal-metal nanojunctions. Phys. Rev. B 46, 5814(R)&#x2212;5817(R) (1992).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR48\" id=\"ref-link-section-d38842562e1911\" rel=\"nofollow noopener\" target=\"_blank\">48<\/a> was observed through I-V curves or a zero-bias conductance peak (ZBCP), reproducing properties of conventional S\/I\/S Josephson junctions. Since the origin of similar ZBCP observations<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 53\" title=\"Kastalsky, A. et al. Observation of pair currents in superconductor-semiconductor contacts. Phys. Rev. Lett. 67, 3026&#x2013;3029 (1991).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR53\" id=\"ref-link-section-d38842562e1921\" rel=\"nofollow noopener\" target=\"_blank\">53<\/a> continues to be studied and attributed to resonant effects<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Bouscher, S. et al. Enhanced Cooper-Pair Injection into a Semiconductor Structure by Resonant Tunneling. Phys. Rev. Lett. 128, 127701 (2022).\" href=\"#ref-CR54\" id=\"ref-link-section-d38842562e1925\">54<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Giazotto, F. et al. Resonant transport in Nb\/GaAs\/AlGaAs heterostructures: Realization of the de Gennes&#x2013;Saint-James model. Phys. Rev. Lett. 87, 216808 (2001).\" href=\"#ref-CR55\" id=\"ref-link-section-d38842562e1925_1\">55<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 56\" title=\"Sengupta, K., &#x17D;uti&#x107;, I., Kwon, H.-J., Yakovenko, V. M. &amp; Das Sarma, S. Midgap edge states and pairing symmetry of a quasi-one-dimensional organic superconductor. Phys. Rev. B 63, 144531 (2001).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR56\" id=\"ref-link-section-d38842562e1928\" rel=\"nofollow noopener\" target=\"_blank\">56<\/a>, even without the proximity-induced second superconducting region, our noise spectroscopy could distinguish various scenarios and detect the proximity-induced Josephson effect. Our focus on a simple and transparent theoretical approach invites future theoretical extensions. Resonant effects alone would not support MAR and preclude our observed giant shot noise. Another ZBCP implication is its signature of Majorana states<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 55\" title=\"Giazotto, F. et al. Resonant transport in Nb\/GaAs\/AlGaAs heterostructures: Realization of the de Gennes&#x2013;Saint-James model. Phys. Rev. Lett. 87, 216808 (2001).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR55\" id=\"ref-link-section-d38842562e1933\" rel=\"nofollow noopener\" target=\"_blank\">55<\/a> in spin-triplet topological superconductivity considered for fault-tolerant quantum computing<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e1937\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 22\" title=\"Flensberg, K., Von Oppen, F. &amp; Stern, A. Engineered platforms for topological superconductivity and Majorana zero modes. Nat. Rev. Mater. 6, 944&#x2013;958 (2021).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR22\" id=\"ref-link-section-d38842562e1940\" rel=\"nofollow noopener\" target=\"_blank\">22<\/a>. However, an extrinsic ZBCP origin remains debated<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 22\" title=\"Flensberg, K., Von Oppen, F. &amp; Stern, A. Engineered platforms for topological superconductivity and Majorana zero modes. Nat. Rev. Mater. 6, 944&#x2013;958 (2021).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR22\" id=\"ref-link-section-d38842562e1944\" rel=\"nofollow noopener\" target=\"_blank\">22<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 57\" title=\"Yu, P. et al. Non-Majorana states yield nearly quantized conductance in proximatized nanowires. Nat. Phys. 17, 482&#x2013;488 (2021).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR57\" id=\"ref-link-section-d38842562e1947\" rel=\"nofollow noopener\" target=\"_blank\">57<\/a>, and shot noise spectroscopy could help to identify Majorana states<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 58\" title=\"Jonckheere, T. et al. Giant shot noise from Majorana zero modes in topological trijunctions. Phys. Rev. Lett. 122, 097003 (2019).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR58\" id=\"ref-link-section-d38842562e1951\" rel=\"nofollow noopener\" target=\"_blank\">58<\/a>.<\/p>\n<p>While Fe\/MgO-based junctions have been extensively studied<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 34\" title=\"Parkin, S. S. P. et al. Giant tunneling magnetoresistance at room temperature with MgO (100) tunnel barriers. Nat. Mater. 3, 862&#x2013;867 (2004).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR34\" id=\"ref-link-section-d38842562e1958\" rel=\"nofollow noopener\" target=\"_blank\">34<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 35\" title=\"Yuasa, S., Nagahama, T., Fukushima, A., Suzuki, Y. &amp; Ando, K. Giant room temperature magneto-resistance in single-crystal Fe\/MgO\/Fe magnetic tunnel junctions. Nat. Mater. 3, 868&#x2013;871 (2004).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR35\" id=\"ref-link-section-d38842562e1961\" rel=\"nofollow noopener\" target=\"_blank\">35<\/a>, from commercial applications<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 59\" title=\"Spintronics Handbook: Spin Transport and Magnetism, 2nd Ed., edited by Tsymbal, E. Y. &amp; &#x17D;uti&#x107;, I.(CRC Press, Boca Raton, FL, 2019).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR59\" id=\"ref-link-section-d38842562e1965\" rel=\"nofollow noopener\" target=\"_blank\">59<\/a> to integrating spintronics, electronics, and photonics<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 60\" title=\"Dainone, P. A. et al. Controlling the helicity of light by electrical magnetization switching. Nature 627, 783&#x2013;788 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR60\" id=\"ref-link-section-d38842562e1969\" rel=\"nofollow noopener\" target=\"_blank\">60<\/a>, there is only a limited understanding of their all-epitaxial growth with superconductors<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e1973\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 31\" title=\"Mart&#xED;nez, I. et al. Interfacial spin-orbit coupling: A platform for superconducting spintronics. Phys. Rev. Appl. 13, 014030 (2020).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR31\" id=\"ref-link-section-d38842562e1976\" rel=\"nofollow noopener\" target=\"_blank\">31<\/a>. Since we show that even in the normal state for these junctions, their resistance is dominated by the symmetry-related SOC barrier (recall Fig.\u00a0<a data-track=\"click\" data-track-label=\"link\" data-track-action=\"figure anchor\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#Fig1\" rel=\"nofollow noopener\" target=\"_blank\">1b<\/a>), rather than the conventional barrier associated with the MgO regions, this motivates further studies to explore the superconducting spintronics in all-epitaxial superconductor junctions with ferromagnets, where the spin-triplet proximity and spin currents could be controlled by SOC. The role of SOC in proximity-induced spin-triplet topological superconductivity is well studied using semiconductor nanostructures<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Amundsen, M., Linder, J. &amp; Robinson, J. W. A. &#x17D;uti&#x107;, I. &amp; Banerjee, N. Colloquium: Spin-orbit effects in superconducting hybrid structures. Rev. Mod. Phys. 96, 021003 (2024).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR17\" id=\"ref-link-section-d38842562e1984\" rel=\"nofollow noopener\" target=\"_blank\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 22\" title=\"Flensberg, K., Von Oppen, F. &amp; Stern, A. Engineered platforms for topological superconductivity and Majorana zero modes. Nat. Rev. Mater. 6, 944&#x2013;958 (2021).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR22\" id=\"ref-link-section-d38842562e1987\" rel=\"nofollow noopener\" target=\"_blank\">22<\/a>, but often overlooked in ferromagnetic junctions<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 21\" title=\"Buzdin, A. I. Proximity effects in superconductor-ferromagnet heterostructures. Rev. Mod. Phys. 77, 935&#x2013;976 (2005).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR21\" id=\"ref-link-section-d38842562e1991\" rel=\"nofollow noopener\" target=\"_blank\">21<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Keizer, R. S. et al. A spin triplet supercurrent through the half-metallic ferromagnet CrO2. Nature 439, 825&#x2013;827 (2006).\" href=\"#ref-CR28\" id=\"ref-link-section-d38842562e1994\">28<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" title=\"Singh, A., Voltan, S., Lahabi, K. &amp; Aarts, J. Colossal proximity effect in a superconducting triplet spin valve based on the half-metallic ferromagnet CrO2. Phys. Rev. X 5, 021019 (2015).\" href=\"#ref-CR29\" id=\"ref-link-section-d38842562e1994_1\">29<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 30\" title=\"Sanchez-Manzano, D. et al. Extremely long- range, high-temperature Josephson coupling across a half-metallic ferromagnet. Nat. Mater. 21, 188&#x2013;194 (2022).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR30\" id=\"ref-link-section-d38842562e1997\" rel=\"nofollow noopener\" target=\"_blank\">30<\/a>. Shot noise spectroscopy could overcome these uncertainties, elucidating the role of SOC in systems where there remains a debate about the induced long-range spin-triplet superconductivity<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 30\" title=\"Sanchez-Manzano, D. et al. Extremely long- range, high-temperature Josephson coupling across a half-metallic ferromagnet. Nat. Mater. 21, 188&#x2013;194 (2022).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR30\" id=\"ref-link-section-d38842562e2001\" rel=\"nofollow noopener\" target=\"_blank\">30<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 61\" title=\"Kalcheim, Y., Kizhner, T., Koren, G. &amp; Millo, O. Long-range proximity effect in La2\/3Ca1\/3MnO3\/ (100)YBa2Cu3O7&#x2212;&#x3B4; ferromagnet\/superconductor bilayers: Evidence for induced triplet superconductivity in the ferromagnet. Phys. Rev. B 83, 064510 (2011).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR61\" id=\"ref-link-section-d38842562e2004\" rel=\"nofollow noopener\" target=\"_blank\">61<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 62\" title=\"Fridman, I., Gunawan, L., Botton, G. A. &amp; Wei, J. Y. T. Scanning tunneling spectroscopy study of c-axis proximity effect in epitaxial bilayer manganite\/cuprate thin films. Phys. Rev. B 83, 104522 (2011).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR62\" id=\"ref-link-section-d38842562e2007\" rel=\"nofollow noopener\" target=\"_blank\">62<\/a>. Our findings also pertain to materials design and emergent phenomena through various proximity effects, where buried interfaces play a crucial role<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 13\" title=\"&#x17D;uti&#x107;, I., Matos-Abiague, A., Scharf, B., Dery, H. &amp; Belashchenko, K. Proximitized materials. Mater. Today 22, 85&#x2013;107 (2019).\" href=\"http:\/\/www.nature.com\/articles\/s41467-025-64493-w#ref-CR13\" id=\"ref-link-section-d38842562e2011\" rel=\"nofollow noopener\" target=\"_blank\">13<\/a>. While probing such interfacial properties poses a challenge for many scanning probes, our work demonstrates that even buried interfaces are directly accessible to noise spectroscopy.<\/p>\n","protected":false},"excerpt":{"rendered":"Our choice of epitaxial V(100)\/MgO\/Fe(100) junctions appears surprising. The incompatible orbital symmetries in the electronic structure of V(100)&hellip;\n","protected":false},"author":2,"featured_media":248169,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[24],"tags":[49,48,3881,1099,1100,314,66,16968,3884],"class_list":{"0":"post-248168","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-physics","8":"tag-ca","9":"tag-canada","10":"tag-electronic-properties-and-materials","11":"tag-humanities-and-social-sciences","12":"tag-multidisciplinary","13":"tag-physics","14":"tag-science","15":"tag-superconducting-devices","16":"tag-superconducting-properties-and-materials"},"_links":{"self":[{"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/posts\/248168","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/comments?post=248168"}],"version-history":[{"count":0,"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/posts\/248168\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/media\/248169"}],"wp:attachment":[{"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/media?parent=248168"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/categories?post=248168"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.newsbeep.com\/ca\/wp-json\/wp\/v2\/tags?post=248168"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}