A team of Chinese scientists has unveiled a breakthrough method that turns carbon dioxide and water into valuable chemicals, including the fundamental components of petrol, using sunlight as the energy source.
Drawing inspiration from photosynthesis – the natural process plants use to convert sunlight, water, and carbon dioxide into energy – the approach aims to create a more sustainable way to produce fuel.
The researchers, coming from the Chinese Academy of Sciences and the Hong Kong University of Science and Technology, created a specialized material capable of storing small amounts of electrical energy, which boosts the efficiency of the chemical reactions needed to transform CO2 into useful compounds.
Advancing solar fuel production with CO2 photoreduction
By combining the system with catalysts that transform carbon dioxide into different chemicals, researchers achieved solar-powered production of carbon monoxide. This intermediate can then be further converted into fuels, presenting a potential alternative for industries that are difficult to electrify, including aviation and shipping.
The team noted in a paper published last week in the peer-reviewed journal Nature Communications that their approach establishes a bioinspired charge reservoir strategy for efficient carbon dioxide photoreduction. They emphasized that this method provides a universal pathway for producing solar fuels, bridging a critical gap between renewable energy and high-demand industrial applications, the South China Morning Post writes.
Interest is growing in the light-driven conversion of carbon dioxide, or photocatalysis, as a promising approach to both reducing greenhouse gas emissions and easing pressure on natural resources, the researchers said. One particularly attractive application lies in producing solar fuels – synthetic fuels generated using sunlight that closely resemble conventional fossil fuels and can work with existing fuel infrastructure.
This process involves transforming carbon dioxide into intermediary chemicals such as carbon monoxide, which can then be further processed into liquid hydrocarbons, offering a potential pathway to create sustainable fuel alternatives without overhauling current energy systems.
Mimicking nature to improve artificial photosynthesis efficiency
Replacing sacrificial agents with water in solar fuel production would be the optimal solution, but it involves connecting multiple complex chemical reactions, including water oxidation and carbon dioxide reduction. Nature, however, performs these processes with remarkable efficiency, using a molecule that temporarily stores photogenerated electrons to facilitate energy transfer.
Drawing inspiration from this natural strategy, the researchers implemented a similar charge storage mechanism in an artificial photosynthetic system, aiming to replicate the efficiency of plants in driving solar-powered chemical transformations.
In an effort to replicate this natural mechanism, the team engineered a silver-modified tungsten trioxide material that can store electrons during light exposure and release them on demand. They reported that the material performs on par with systems using organic sacrificial agents and offers “universal applicability” when combined with a range of different catalysts.
Testing the material under sunlight, the team found that natural light could trigger the reaction, paving the way for solar fuel applications. They noted that this approach removes the need for unsustainable sacrificial agents while offering a versatile design principle for building efficient, stand-alone photocatalytic systems.