City’s Doku and Rayan Ait-Nouri and Real Madrid’s Federico Valverde and Vinicius had second-half goals chalked off before Vinicius completed his brace with the last kick of the game from the edge of the six-yard box in the 93rd minute. The Spaniards, 15-times winners of Europe’s elite club competition, had stunned 2023 champions Manchester City 3-0 in last week’s first leg in Madrid when Valverde struck a hat-trick.