Oyakhire, S. T., Gong, H., Cui, Y., Bao, Z. & Bent, S. F. An X-ray photoelectron spectroscopy primer for solid electrolyte interphase characterization in lithium metal anodes. ACS Energy Lett. 7, 2540\u20132546 (2022).<\/p>\n
CAS<\/a>\u00a0 Yu, W., Yu, Z., Cui, Y. & Bao, Z. Degradation and speciation of Li salts during XPS analysis for battery research. ACS Energy Lett. 7, 3270\u20133275 (2022).<\/p>\n CAS<\/a>\u00a0 Bard, A. J. et al. ChemInform Abstract: the electrode\/electrolyte interface – a status report. J. Phys. Chem. 97, 7147\u20137173 (1993).<\/p>\n CAS<\/a>\u00a0 Yu, X. & Manthiram, A. Electrode-electrolyte interfaces in lithium-based batteries. Energy Environ. Sci. 11, 527\u2013543 (2018).<\/p>\n CAS<\/a>\u00a0 Stamenkovic, V. R., Strmcnik, D., Lopes, P. P. & Markovic, N. M. Energy and fuels from electrochemical interfaces. Nat. Mater. 16, 57\u201369 (2017).<\/p>\n ADS<\/a>\u00a0 Lin, D., Liu, Y. & Cui, Y. Reviving the lithium metal anode for high-energy batteries. Nat. Nanotechnol. 12, 194\u2013206 (2017).<\/p>\n ADS<\/a>\u00a0 Li, Y., Leung, K. & Qi, Y. Computational exploration of the Li-electrode|electrolyte interface in the presence of a nanometer thick solid-electrolyte interphase layer. Acc. Chem. Res. 49, 2363\u20132370 (2016).<\/p>\n CAS<\/a>\u00a0 Winter, M. The solid electrolyte interphase \u2013 the most important and the least understood solid electrolyte in rechargeable Li batteries. Z. Phys. Chem. 223, 1395\u20131406 (2009).<\/p>\n CAS<\/a>\u00a0 Dedryv\u00e8re, R. et al. XPS identification of the organic and inorganic components of the electrode\/electrolyte interface formed on a metallic cathode. J. Electrochem. Soc. 152, A689 (2005).<\/p>\n Kanamura, K., Tamura, H., Shiraishi, S. & Takehara, Z.-I. XPS analysis for the lithium surface immersed in \u03b3-butyrolactone containing various salts. J. Electrochem. Soc. 40, 913\u2013921 (1995).<\/p>\n CAS<\/a>\u00a0 Andersson, A. M. & Edstr\u00f6m, K. Chemical composition and morphology of the elevated temperature SEI on graphite. J. Electrochem. Soc. 148, A1100 (2001).<\/p>\n CAS<\/a>\u00a0 Li, Y. et al. Atomic structure of sensitive battery materials and interfaces revealed by cryo-electron microscopy. Science 358, 506\u2013510 (2017).<\/p>\n ADS<\/a>\u00a0 Boyle, D. T. et al. Corrosion of lithium metal anodes during calendar ageing and its microscopic origins. Nat. Energy 6, 487\u2013494 (2021).<\/p>\n ADS<\/a>\u00a0 Steinr\u00fcck, H. G. et al. Interfacial speciation determines interfacial chemistry: X-ray-induced lithium fluoride formation from water-in-salt electrolytes on solid surfaces. Angew. Chem. Int. Ed. 59, 23180\u201323187 (2020).<\/p>\n Zhang, Z. et al. Capturing the swelling of solid-electrolyte interphase in lithium metal batteries. Science 375, 66\u201370 (2022).<\/p>\n ADS<\/a>\u00a0 Wang, X. et al. New insights on the structure of electrochemically deposited lithium metal and its solid electrolyte interphases via cryogenic TEM. Nano Lett. 17, 7606\u20137612 (2017).<\/p>\n ADS<\/a>\u00a0 Zachman, M. J., Tu, Z., Choudhury, S., Archer, L. A. & Kourkoutis, L. F. Cryo-STEM mapping of solid\u2013liquid interfaces and dendrites in lithium-metal batteries. Nature 560, 345\u2013349 (2018).<\/p>\n ADS<\/a>\u00a0 Zhang, Z. et al. Cryogenic electron microscopy for energy materials. Acc. Chem. Res. 54, 3505\u20133517 (2021).<\/p>\n CAS<\/a>\u00a0 Bai, X., McMullan, G. & Scheres, S. H. W. How cryo-EM is revolutionizing structural biology. Trends Biochem. Sci 40, 49\u201357 (2015).<\/p>\n CAS<\/a>\u00a0 Dubochet, J. On the development of electron cryo-microscopy (Nobel Lecture). Angew. Chem. Int. Ed. 130, 10842\u201310846 (2018).<\/p>\n Henderson, R. From electron crystallography to single particle CryoEM (Nobel Lecture). Angew. Chem. Int. Ed. 130, 10804\u201310825 (2018).<\/p>\n Taylor, K. A. & Glaeser, R. M. Electron diffraction of frozen, hydrated protein crystals. Science 186, 1036\u20131037 (1974).<\/p>\n ADS<\/a>\u00a0 McDowall, A. W. et al. Electron microscopy of frozen hydrated sections of vitreous ice and vitrified biological samples. J. Microsc. 131, 1\u20139 (1983).<\/p>\n CAS<\/a>\u00a0 Henderson, R., Baldwin, J. M., Downing, K. H., Lepault, J. & Zemlin, F. Structure of purple membrane from Halobacterium halobium: recording, measurement and evaluation of electron micrographs at 3.5\u2009\u00c5 resolution. Ultramicroscopy 19, 147\u2013178 (1986).<\/p>\n CAS<\/a>\u00a0 Fernandez-Moran, H. Cell-membrane ultrastructure: low-temperature electron microscopy and X-ray diffraction studies of lipoprotein components in lamellar systems. Circulation 26, 1039\u20131065 (1962).<\/p>\n CAS<\/a>\u00a0 Tan, J., Matz, J., Dong, P., Shen, J. & Ye, M. A. A growing appreciation for the role of LiF in the solid electrolyte interphase. Adv. Energy Mater. 11, 2100046 (2021).<\/p>\n CAS<\/a>\u00a0 Li, T., Zhang, X.-Q., Shi, P. & Zhang, Q. Fluorinated solid-electrolyte interphase in high-voltage lithium metal batteries. Joule 3, 2647\u20132661 (2019).<\/p>\n CAS<\/a>\u00a0 Wang, C., Meng, Y. S. & Xu, K. Perspective\u2014fluorinating Interphases. J. Electrochem. Soc. 166, A5184\u2013A5186 (2019).<\/p>\n CAS<\/a>\u00a0 Hobold, G. M., Wang, C., Steinberg, K., Li, Y. & Gallant, B. M. High lithium oxide prevalence in the lithium solid\u2013electrolyte interphase for high Coulombic efficiency. Nat. Energy 9, 580\u2013591 (2024).<\/p>\n ADS<\/a>\u00a0 Kim, M. S. et al. Suspension electrolyte with modified Li+ solvation environment for lithium metal batteries. Nat. Mater. 21, 445\u2013454 (2022).<\/p>\n ADS<\/a>\u00a0 Lin, D. et al. Fast galvanic lithium corrosion involving a Kirkendall-type mechanism. Nat. Chem. 11, 382\u2013389 (2019).<\/p>\n ADS<\/a>\u00a0 Arkel, A. E., Spitsbergen, U. & Heyding, R. D. Note on the volatility of lithium oxide. Can. J. Chem. 33, 446\u2013447 (1955).<\/p>\n ADS<\/a>\u00a0 Kudo, H., Wu, C. H. & Ihle, H. R. Mass-spectrometric study of the vaporization of Li2O(s) and thermochemistry of gaseous LiO, Li2O, Li3O, and Li2O2. J. Nucl. Mater. 78, 380\u2013389 (1978).<\/p>\n ADS<\/a>\u00a0 Seah, M. P. & Dench, W. A. Quantitative electron spectroscopy of surfaces: a standard data base for electron inelastic mean free paths in solids. Surf. Interface Anal. 1, 2\u201311 (1979).<\/p>\n CAS<\/a>\u00a0 D\u2019Acunto, G. et al. Atomic layer deposition of hafnium oxide on InAs: insight from time-resolved in situ studies. ACS Appl. Electron Mater 2, 3915\u20133922 (2020).<\/p>\n Walther, T. in Microscopy Methods in Nanomaterials Characterization 105\u2013134 (Elsevier, 2017).<\/p>\n Garc\u00eda De Abajo, F. J. & Di Giulio, V. Optical excitations with electron beams: challenges and opportunities. ACS Photon. 8, 945\u2013974 (2021).<\/p>\n Jagger, B. & Pasta, M. Solid electrolyte interphases in lithium metal batteries. Joule 7, 2228\u20132244 (2023).<\/p>\n CAS<\/a>\u00a0 He, M., Guo, R., Hobold, G. M., Gao, H. & Gallant, B. M. The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium. Proc. Natl Acad. Sci. USA 117, 73\u201379 (2019).<\/p>\n ADS<\/a>\u00a0 Kim, M. S. et al. Revealing the multifunctions of Li3N in the suspension electrolyte for lithium metal batteries. ACS Nano 17, 3168\u20133180 (2023).<\/p>\n CAS<\/a>\u00a0 Spearman, C. The proof and measurement of association between two things. Am. J. Psychol. 15, 72\u2013101 (1904).<\/p>\n Oyakhire, S. T. et al. Proximity matters: interfacial solvation dictates solid electrolyte interphase composition. Nano Lett. 23, 7524\u20137531 (2023).<\/p>\n ADS<\/a>\u00a0 Oyakhire, S. T. & Bent, S. F. Interfacial engineering of lithium metal anodes: what is left to uncover? Energy Adv. 3, 108\u2013122 (2023).<\/p>\n Yu, Z. et al. Rational solvent molecule tuning for high-performance lithium metal battery electrolytes. Nat. Energy 7, 94\u2013106 (2022).<\/p>\n ADS<\/a>\u00a0 Peled, E., Golodnitsky, D. & Ardel, G. Advanced model for solid electrolyte interphase electrodes in liquid and polymer electrolytes. J. Electrochem. Soc. 144, L208 (1997).<\/p>\n CAS<\/a>\u00a0 Cui, Z. et al. Molecular anchoring of free solvents for high-voltage and high-safety lithium metal batteries. Nat. Commun. 15, 2033 (2024).<\/p>\n ADS<\/a>\u00a0 Zhang, W. et al. Recovery of isolated lithium through discharged state calendar ageing. Nature 626, 306\u2013312 (2024).<\/p>\n ADS<\/a>\u00a0 Otto, S.-K. et al. In-depth characterization of lithium-metal surfaces with XPS and ToF-SIMS: toward better understanding of the passivation layer. Chem. Mater. 33, 859\u2013867 (2021).<\/p>\n ADS<\/a>\u00a0 Baer, D. R. XPS guide: charge neutralization and binding energy referencing for insulating samples. J. Vac. Sci. Technol. A 38, 031204 (2020).<\/p>\n CAS<\/a>\u00a0 Greczynski, G. & Hultman, L. Compromising science by ignorant instrument calibration\u2014need to revisit half a century of published XPS data. Angew. Chem. Int. Ed. 59, 5002\u20135006 (2020).<\/p>\n CAS<\/a>\u00a0 Liu, Q. et al. A fluorinated cation introduces new interphasial chemistries to enable high-voltage lithium metal batteries. Nat. Commun. 14, 3678 (2023).<\/p>\n ADS<\/a>\u00a0 Ge, S. et al. High safety and cycling stability of ultrahigh energy lithium ion batteries. Cell Rep. Phys. Sci. 2, 100584 (2021).<\/p>\n CAS<\/a>\u00a0 Wood, K. N. & Teeter, G. XPS on Li-battery-related compounds: analysis of inorganic SEI phases and a methodology for charge correction. ACS Appl. Energy Mater. 1, 4493\u20134504 (2018).<\/p>\n CAS<\/a>\u00a0 Rustomji, C. S. et al. Liquefied gas electrolytes for electrochemical energy storage devices. Science 356, eaal4263 (2017).<\/p>\n PubMed<\/a>\u00a0 Ren, X. et al. Enabling high-voltage lithium-metal batteries under practical conditions. Joule 3, 1662\u20131676 (2019).<\/p>\n CAS<\/a>\u00a0 Templeton, D. M. et al. Guidelines for terms related to chemical speciation and fractionation of elements. Definitions, structural aspects, and methodological approaches (IUPAC recommendations 2000). Pure Appl. Chem. 72, 1453\u20131470 (2009).<\/p>\n Feldmann, J. et al. Microwave-assisted sample preparation for element speciation. in Microwave-Assisted Sample Preparation for Trace Element Determination 281\u2013312 (Elsevier, 2014).<\/p>\n Greczynski, G. & Hultman, L. Towards reliable X-ray photoelectron spectroscopy: sputter-damage effects in transition metal borides, carbides, nitrides, and oxides. Appl. Surf. Sci. 542, 148599 (2021).<\/p>\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n PubMed Central<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n PubMed Central<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n CAS<\/a>\u00a0
\n PubMed<\/a>\u00a0
\n PubMed Central<\/a>\u00a0
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n
\n
\n Google Scholar<\/a>\u00a0\n <\/p>\n","protected":false},"excerpt":{"rendered":"Oyakhire, S. T., Gong, H., Cui, Y., Bao, Z. & Bent, S. F. An X-ray photoelectron spectroscopy primer…\n","protected":false},"author":2,"featured_media":244907,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32],"tags":[46121,15877,1159,1160,79],"class_list":{"0":"post-244906","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-science","8":"tag-batteries","9":"tag-characterization-and-analytical-techniques","10":"tag-humanities-and-social-sciences","11":"tag-multidisciplinary","12":"tag-science"},"_links":{"self":[{"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/posts\/244906","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/comments?post=244906"}],"version-history":[{"count":0,"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/posts\/244906\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/media\/244907"}],"wp:attachment":[{"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/media?parent=244906"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/categories?post=244906"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.newsbeep.com\/us\/wp-json\/wp\/v2\/tags?post=244906"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}